Space charge and conductivity

DC Conductivity Measurement System

The laboratory is equipped with a DC conductivity measurement system designed for the electrical characterization of insulating materials under controlled temperature and electric field conditions. The setup enables the precise determination of the conductivity and resistivity of dielectric materials, providing essential information on charge transport processes and insulation performance.

Particular emphasis is placed on the investigation of polymeric insulation systems for high-voltage and HVDC applications. The facility supports studies on the influence of temperature, electric field, aging, moisture, and material formulation on the conductive behavior of polymers and dielectric nanocomposites.

Applications:

  • Voltages up to 35 kV DC
  • Currents as low as 0.1 pA
  • Electrical characterization of polymeric insulating materials
  • Conductivity and resistivity measurements under DC stress
  • Evaluation of temperature-dependent conduction behavior
  • Assessment of aging and degradation effects
  • Investigation of moisture influence on insulation performance
  • Characterization of dielectric nanocomposites and advanced insulation systems
  • Research and development of materials for power transmission and energy applications

Space Charge Investigation by Pulsed Electroacoustic (PEA) Method

The Pulsed Electroacoustic (PEA) method is a powerful diagnostic technique used to measure and visualize the space charge distribution within dielectric and insulating materials subjected to an electric field. By applying short voltage pulses to a polarized sample, the technique detects acoustic waves generated by trapped charges, allowing the reconstruction of the charge profile across the material thickness.

PEA is particularly important for the characterization of polymeric insulation systems, where space charge accumulation can significantly influence electric field distribution, accelerate aging processes, and ultimately reduce insulation reliability. The technique provides direct information on charge injection, transport, trapping, and accumulation mechanisms, supporting the development of advanced insulating materials for high-voltage applications.

Key capabilities:

  • Direct measurement of space charge distribution in dielectric materials
  • Investigation of charge injection, transport, trapping, and detrapping phenomena
  • Assessment of electric field distortion caused by accumulated charges
  • Evaluation of aging and degradation mechanisms in insulation systems
  • Analysis of the effects of temperature, electric field, and material formulation
  • Characterization of polymeric dielectrics, nanocomposites, and cable insulation materials
  • Support for lifetime prediction and reliability assessment of electrical insulation
  • Development of high-performance insulating materials for power transmission and energy applications

PEA measurements are widely applied to high-voltage polymeric insulations, including cable dielectrics, nanostructured insulating materials, and advanced electrical insulation systems, where understanding space charge behavior is essential for improving performance, safety, and long-term reliability.

TSDC – Thermally Stimulated Depolarization currents

This is a relaxation technique for investigation of molecular mobility in the solid state with sensitivity comparable to DMA.

Materials: semiconductors, polymers, polymer-clay composites.

Provides information on

  • trap centers and corresponding thermal activation energies
  • trap concentrations.

Operating principle: Thermal detrapping of carriers from defects causes peaks in the leakage current at certain temperatures corresponding to specific trapping centers.

Sensitivity: Densities of electronically active traps as low as 109 cm−3 can easily be detected in high resistivity materials.

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