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MOLCAT Research interests and activities

Transition metal chemistry plays a vital role in advancing catalysis and sustainable chemical processes, significantly impacting energy, industry, and environmental applications. The design and synthesis of transition metal complexes, particularly those based on elements such as ruthenium, iron, silver, and rhodium, have enabled the development of efficient catalytic systems for key transformations. Our research focuses on exploring homogeneous catalysis and bio-inorganic chemistry using innovative ligand frameworks, including N-heterocyclic carbenes and cyclopentadienones, to drive reactions relevant to energy transition and the circular economy. These catalysts facilitate processes such as selective hydrogenation, biomass valorization, and electrochemical transformations, including water oxidation and hydrogen evolution. By combining experimental techniques such as spectroscopy, electrochemistry, and mechanistic studies, we aim to develop sustainable catalytic solutions for industrial and environmental challenges.

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Advances in Electrocatalyzed Water Oxidation by Molecular Complexes of First Row Transition Metals

Chiara Lenzi, Andrea Masetti, Isacco Gualandi, Erika Scavetta, Luca Rigamonti, Rita Mazzoni

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Advances in the homogeneously catalyzed hydrogen production from biomass derived feedstocks: a review

Andrea Fasolini, Giulia Martelli, Andrea Piazzi, Massimiliano Curcio, Japoco De Maron, Francesco Basile, Rita Mazzoni

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Combined computational-experimental study of Ru(0)-catalyzed Guerbet reaction

Francesco Calcagno, Cristiana Cesari, Anna Gagliardi, Alessandro Messori, Andrea Piazzi, Filippo Tamassia, Marco Garavelli, Fahmi Himo, Rita Mazzoni, Ivan Rivalta

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Ethanol to gasoline and sustainable aviation fuel precursors: an innovative cascade strategy over Zr-based multifunctional catalysts in the gas phase

Anna Gagliardi, Giulia Balestra, Jacopo De Maron, Rita Mazzoni, Tommaso Tabanelli, Fabrizio Cavani

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Role of alkylated 2,6-bis(tetrazol-5-yl)pyridyl ligands and Iron(II) salts in selecting spin crossover complexes

Rita Mazzoni, Stefano Baratti, Daniel Rustichelli, Stefano Stagni, Valentina Fiorini, Stefano Zacchini, Dawid Pinkowicz, Alessandra Forni, Jasper R. Plaisier, Lara Gigli, Luca Rigamonti

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